In the 1930s as steam generator technology evolved and high-pressure units grew in numbers, tri-sodium phosphate (TSP, Na 3 PO 4) became the common chemical for boiler water treatment as it generates alkalinity (caustic, NaOH) to protect against corrosion. Also, phosphate reacts with hardness compounds to reduce the scaling tendencies of some impurities.
Foaming of water in the boiler a) is due to a high concentration of dissolved gases b) can be controlled by adding sodium phosphate c) can be controlled by adding more neutralizing amines
However, in high-purity water systems, such as is used for supercritical boilers, the controlled addition of oxygen during operation is beneficial as it reduces corrosion product transport to the boiler and subsequently reduces the rate of deposition within the boiler.
utility boiler experienced severe internal furnace tube corrosion. The attack encompassed the fire side of tubes in all four walls of the furnace in the burner zone. Major quantities of sodium iron phosphate were found in the affected tubes, indicating that the sodium phosphate from the boiler water had participated in the corrosion mechanism.
Corrosion Prevention in Steam Boiler Systems. The cost of boiler repairs due to corrosion can be in the order of $50,000 to over $1m, plus cost of time off hire. These significant costs often go unrecognized as many are covered by insurance claims. However, in the end, the marine industry will bear the cost, reflected back in higher insurance and deductible costs.
Actually for high pressure boilers especially at 120 bar, with a demineralized make-up water, coordinated pH/PO 4 treatment is mainly for caustic corrosion protection. Again, the PO4 to sodium (Na) ratio is NOT 3:1 but should be between 2.2 - 2.8 to 1, best at about 2.5 - 2.6 to 1.
generally classified as low-pressure (ahead of the deaerator), high-pressure (after the deaerator), or deaerating heaters. Regardless of feed water heater design, the major problems are similar for all types. The primary problems are corrosion, due to oxygen and improper pH, and erosion from the tube side or the shell side.
What is the correct pressure for a boiler? While not every boiler has the same pressure requirements, most central heating systems perform within the range of 1 to 2 bar, which is between 14 and 29 pounds per square inch (psi). The exact pressure of your combination and system boiler can be measured on the boiler pressure gauge, which is generally visible on the front of the control panel. How to top up the pressure on boilers
Boiler Water Phosphate Chemistry 00 Purpose The purpose of this bulletin is to re-emphasize to all utility operators the potential chemistry control prob- lems that can lead to serious furnace tube corrosion. Monitoring of boiler water chemicals has always been necessary. However, units operating at high drum pressures require even closer
Water Quality in High Pressure Boilers. Silica, in ppm to be controlled in such a way in boiler water so that it will be less than 0.02 ppm in steam for pressure range 61-165 kg/cm2. For pressure range 166-205 silica in boiler water to be kept below 0.10 ppm.
iron and steel components are caused by excessive oxygen in the boiler/feedwater. The accumulations of corrision products covered by unique nodules are called “tubercles.” 2.2.5 Iron, eaten away by “acid rain” and oxygen corrosion, is transported to the boiler, where it becomes an insulating deposit. It restricts heat transfer, which can
High pressure boilers (operating above 60 kg/cm2(g)) are normally designed close to the limiting conditions of the heat transfer, tube metal temperature, circulation etc. to make the units compact and economical. The principal problem in modern high pressure boilers is the control of corrosion and steam quality.
Oct 12, 2015 · Increase cut off pressure of boiler. Bypass high pressure cut off of the boiler. Arrange the boiler fire rate to a maximum. Safety valve will be lift during the test. The test is carried out as long as the water permits in the boiler. Accumulation pressure should not exceed 10% of working pressure in the specified time. Specified time is 15 mins for a smoke tube boiler and 7 mins for water tube boiler.
Steam and water analysis system is designed for corrosion control in boiler and turbine in power station. To protect equipment from corrosion SWAS work in stages like Sample Extracting, Sample Transport, Sample Conditioning, and sample Analysis.
History of Coordinated Phosphate pH Control • Shoreside high pressure systems experienced failures from localized caustic concentrations in 1930’s and 1940’s – Excess hydrate alkalinity led to metal damage in the form of caustic embrittlement (cracking) or gouging • New boiler water treatment was developed using the alkalinity
feedwater, condensate, and high-pressure boiler water requires direct monitoring of pH. Control of pH is important for the following reasons: • corrosion rates of metals used in boiler systems are sensitive to variations in pH • low pH or insufficient alkalinity can result in corrosive acidic attack
Make-up water to steam boilers should be treated with oxygen scavengers to avoid serious corrosion problems. Corrosion is a major problem in steam systems with high consumption of make-up water. Fresh water contains dissolved oxygen. Oxygen together with high temperature is highly corrosive for the carbon steel piping used in steam systems. To
Hydrogen embrittlement of mild steel boiler tubing occurs in high-pressure boilers when atomic hydrogen forms at the boiler tube surface as a result of corrosion. Hydrogen permeates the tube metal, where it can react with iron carbides to form methane gas, or with other hydrogen atoms to form hydrogen gas.
Oct 13, 2015 · To prevent corrosion in boiler and feed system. To control the sludge formation and prevention of carry over with the steam. To maintain the boiler water in alkaline condition and free from dissolved gases. To prevent of entry into the boiler of foreign matter such as oil, waste, mill scale, FeO, Cu, Sand, etc. Reference:
H1 Dissolved Gases and Dissolved Oxygen Corrosion Control The dissolved gases present in water, specifically oxygen, cause boiler water systems prone to problems with dissolved oxygen corrosion if gone untreated.
Fire Tube Boilers. Also referred to as smoke tube boilers, shell boilers, package boilers Multiple gas paths - 2, 3 and 4 pass Internal furnace or fire box as the 1st pass Dry back or wet back design Single fuel or dual fuel design Little or no steam separation equipment.
The pressure vessel of a boiler is usually made of steel (or alloy steel), or historically of wrought iron. Stainless steel, especially of the austenitic types, is not used in wetted parts of boilers due to corrosion and stress corrosion cracking.
High and Low Pressure Boilers. type of globe valve that allows a boiler to be cut in on-line automatically when the boiler pressure is at or above the header pressure and allows the boiler to be taken off-line automatically.
The correct pH measurement is essential to water treatment: pH too high or too low can lead to boiler or steam turbine scaling and corrosion, system failures, and downtime, as well as the costly
High concentrations of sodium phosphate and sodium hydroxide were used for conditioning drum boilers in the 1950`s. However, corrosion occurred in the new high pressure plant, due to hydrogen damage and caustic gouging. This led to sodium hydroxide being abandoned in the USA in favour of phosphate treatment (PT).
This report is the second in a series of three describing the progress of “A Research Study on Internal Corrosion of High Pressure Boilers.” The first progress report, presented by H. A. Klein and J. K. Rice at the 1965 Annual Meeting of the ASME, describes the background, scope, and organization of the program as well as the test facility.
Maintaining Water Quality in High-Pressure Boilers . Dissolved oxygen, or DO, is one of the most important water quality parameters to control in a boiler system. It is the primary corrosive agent of steam-generating systems. Even low concentrations of DO can be highly destructive, causing localized corrosion and pitting of metal system components.
Oct 12, 2015 · This test is carried out a new boiler or new safety valve. Shut off feed water Closed main steam stop valve. Increase cut off pressure of boiler. Bypass high pressure cut off of the boiler. Arrange the boiler fire rate to a maximum. Safety valve will be lift during the test. The test is carried out as long as the water permits in the boiler.
Once the Boiler pressure is raised to 10 kg/ cm2 (g) stop the pump and observe the pressure drop. Boiler Hydrostatic testing pressure gauge. If no leakage is observed to the satisfaction of the inspecting personnel, start the pressurizing pump. Raise the pressure gradually to 25% of the hydro test pressure and repeat the above steps.
May 05, 2015 · Boiler Chemistry Control and Treatment of Feed Water. In supercritical plants as well as in subcritical plants with CPU, after start up Oxygen Treatment (OT) is done. This treatment feeds Oxygen to Condensate & FW to arrest corrosion as well as internal scale formation—hence less chemical cleaning and quicker start up.
product in the high pressure boiler water in the affected units. The deposits in the front of the high pressure generating bank could lead to overheating failures or under deposit corrosion failures in these tubes. Boiler Internal Surface Passivation Waterside metal surface passivation in an operating boiler is a slow controlled corrosion process,
Accepta 2344 is a high performance corrosion inhibitor scientifically formulated for use in steam boilers, condensate systems and high pressure hot water systems.
In most low pressure industrial boiler systems, if oxygen remains in the feedwater and enters the boiler, it is too late to remove all of the oxygen and protect the boiler and condensate from oxygen corrosion. A residual of sulfite or other oxygen scavenger in the boiler cannot chemically reduce all of the oxygen before it escapes with the steam or
Is my boiler pressure too high? Marco Whenever you’re looking to install a new boiler or simply have maintenance done on your current model, it’s vitally important to know how a boiler loses pressure, and how to repressurise a boiler should you be faced with this issue.
In the case of boilers, corrosion is usually the conversion of steel into soluble or insoluble iron compounds by oxygen pitting corrosion of the tubes and preboiler section, by acid corrosion in the condensate return system or, less commonly, by electrochemical corrosion. Boiler water treatment is therefore necessary to prevent carryover of
corrosion reaction to occur or continue are reduced. H3 The role of Temperature in reducing dissolved oxygen Temperature is another important factor for helping to control dissolved oxygen corrosion in pre-boiler and boiler systems. As temperature increases the solubility of oxygen within that water will be decreased.
ABSTRACT Boiler treatment chemistry has been shown to be critical in maintaining clean heat transfer surfaces and minimizing corrosion in higher pressure industrial boilers. Monitoring boiler feedwater contamination, especially iron and copper, from condensate leakage and upsets is a critical parameter required to maintain control parameters which promote passivation and clean heat transfer surfaces.
maintaining the alkalinity high enough to minimize corrosion of carbon steel. The concentration of phosphate in boilers water is dependent on drum pressure and water quality, a typical high pressure boiler fed with de-mineralized water would tend to run with low concentration of 1 to 5 mg/l range, while a lower
Apr 27, 2015 · Low and medium pressure boilers must be protected from scale deposition and corrosion to promote optimum energy efficiency and prolong the useful life of the plant equipment. The definition of low and medium pressure is somewhat discretionary. For the purposes of this discussion, low pressure shall apply to boilers up to 150 psig.
For good corrosion control in a boiler, rapid reaction is sought between oxygen and the chemical scavenger. A slow reaction rate could allow traces of oxygen to enter the boiler even in the presence of an excess of sodium sulfite. Factors determining the rate at which this reaction takes